Asymmetric membrane fiber-based carbon dioxide removal devices for ion chromatography

The application of hollow and filament-filled single asymmetric membrane fibers, consisting of a thin silicone layer on a tubular microporous support, for removing CO(2) in suppressed ion chromatography effluents is described. With appropriate choice of the removal device and operating conditions, the CO(2) can be essentially quantitatively (99+%) removed. For carbonate-based eluents, the use of such devices greatly reduces or eliminates the water dip, permitting better quantitation of poorly retained anions that elute close to the dip, allows practical gradient chromatography, and improves noise levels and attainable detection limits. In hydroxide eluent chromatography, the device largely removes the response from CO(2) present in the samples; this greatly aids atmospheric trace gas analysis by IC. Device dimensions are such that the dispersion introduced by the device is small.     

High resolution estimation for sub-gaussian stable signals in a linear array model

The authors describe a high resolution subspace fitting (HRE) algorithm for robust estimation of direction of arrival (DOA) in the uniform linear array model with heavy-tailed signals and noise. Electromagnetic disturbances on telephone lines, atmospheric noise and underwater acoustic noise often exhibit heavy-tailed behaviour with differing characteristics. Although statistical models under Gaussian assumptions of signals and noise have been extensively investigated in the literature, there is limited research on robust methods in the non-Gaussian setting. A general model with sub-Gaussian alpha-stable signals is described, which includes the isotropic alpha-stable, and independent and dependent Gaussian models as special cases. It is shown that the HRE algorithm provides strongly consistent estimates of the DOAs. In addition, Monte Carlo simulation studies show that the proposed algorithm works extremely well for closely spaced targets, and outperforms the multiple signal classification-type algorithms for strongly dependent signals, both in the stable and the Gaussian cases     

Transparent hashing in the encrypted domain for privacy preserving image retrieval

Search through a database of encrypted images against a crumpled and encrypted query will remain privacy preserving only if comparisons between selective features derived from these images is executed in the encrypted domain itself. To facilitate this, the encryption process must remain transparent to specific image statistics computed in the spatial or transform domain. Consequently, the perceptual hash formed by quantizing the image statistics remains the same before and after the encryption process. In this paper, we propose a transparent privacy preserving hashing scheme tailored to preserve the DCT-AC coefficient distributions, despite a constrained inter-block shuffling operation. These DCT distributions can be mapped onto a generalized Gaussian model characterized by shape and scale parameters, which can be quantized and Gray-coded into a binary hash matrix. The encryption scheme has been shown to be perceptually secure and does not impair the search reliability and accuracy of the hashing procedure. Experimental results have been provided to verify the robustness of the hash to content-preserving transformations, while demonstrating adequate sensitivity to discriminate between different images.     

Efficient reliability estimate of passive thermal hydraulic safety system with automatic differentiation

An approach for efficient estimation of passive safety system functional reliability has been developed and applied to a simplified model of the passive residual heat transport system typical of sodium cooled fast reactors to demonstrate the reduction in computational time. The method is based on generating linear approximations to the best estimate computer code, using the technique of automatic reverse differentiation. This technique enables determination of linear approximation to the code in a few runs independent of the number of input variables for each response variable. The likely error due to linear approximation is reduced by augmented sampling through best estimate code in the neighborhood of the linear failure surface but in a sub domain where linear approximation error is relatively more. The efficiency of this new approach is compared with importance sampling MCS which uses the linear approximation near the failure region and with Direct Monte-Carlo Simulation. In the importance sampling MCS, variants employing random sampling with Box-Muller algorithm and Markov Chain algorithm are inter-compared. The significance of the results with respect to system reliability is also discussed.     

Clay-catalysed dealkylation of organic sulfides

Both K10- as well as modified montmorillonites such as cation-exchanged and surfactant-pillared clays catalyse the cleavage of carbon–sulfur single bonds resulting in dealkylation of organic sulfides. The corresponding disulfides are obtained in high yield. This revised version was published online in July 2006 with corrections to the Cover Date.     

PYRENE ENCAPSULATED ALGINATE BEAD TYPE FOR SUSTAINED RELEASE IN BIODEGRADATION: PREPARATION AND CHARACTERISTICS

A novel method for preparation of pyrene encapsulated alginate beads for controlled release delivery of pyrene is reported in this study. Five different bead types that varied on the organic phase for pyrene delivery, presence or absence of polyvinyl alcohol (PVA) and boric acid treatment were prepared. Based on the pyrene release profile, silicone oil encapsulated in PVA-alginate bead was selected where encapsulation efficiency was more than 99% without any solvent leakage. Silicone oil encapsulation was further confirmed in microscopy observations. Pyrene release behavior from the beads was explained by a diffusion controlled first order release (R² > 0.96). Reusability of this bead was demonstrated, where pyrene was loaded from an external medium in a non-destructive way. Application of the system was finally established in a biodegradation study using Mycobacterium frederiksbergense, where simultaneous release and removal of pyrene along with appearance of pyrene metabolites was observed.     

Purification, crystallisation and preliminary X-ray diffraction study of ribosome inactivating protein: saporin

OBJECTIVES: To compare transesophageal atrial pacing stress echocardiography with dobutamine stress echocardiography for feasibility, safety, duration, patient acceptance and concordance in inducing wall motion abnormalities. BACKGROUND: Transesophageal atrial pacing is an effective method of increasing heart rate and has been used in the assessment of coronary artery disease. METHODS: Both tests were performed in sequence on the same patients in random order. Transesophageal atrial pacing stress echocardiography began at a heart rate of 10 beats/min above the baseline value and was increased by 20 beats/min every two min until 85% of the age-predicted maximum heart rate or another end point was reached. Dobutamine echocardiography was performed using three-min stages and a maximum dose of 40 microg/kg per min. Atropine (total dose < or =2 mg) was administered at the start of the 40 microg/kg per min stage if needed to augment heart rate or during pacing if Wenckebach heart block occurred. RESULTS: Transesophageal atrial pacing stress echocardiography was feasible in 100 of 104 patients (96%); the duration (8.6+/-3.6 min) was significantly shorter than that of dobutamine stress echocardiography (15.1+/-3.9 min) (p = 0.0001). With transesophageal atrial pacing stress echocardiography, the recovery period was shorter, symptoms and dysrhythmias were fewer, hypertension and hypotension were less common and target heart rate was more frequently achieved. No complications occurred with either test. Patient acceptance was satisfactory. Agreement between results of both tests was good for segmental wall motion scoring with a 16-segment model, scores 1 to 5 (kappa: rest, 0.79; peak, 0.57) and test interpretation (normal, ischemia, infarction or resting wall motion abnormality with ischemia) (kappa: 0.77). CONCLUSIONS: Transesophageal atrial pacing stress echocardiography is a feasible, well-tolerated alternative to dobutamine stress echocardiography. It can be performed rapidly and shows good agreement with dobutamine stress echocardiography in the induction of myocardial ischemia.     

A computational process for choosing the relaxation parameter in nonlinear SOR

We present here a computational process which establishes the convergence of nonlinear successive-overrelaxation in finding the minimum of a strictly convex functional. The algorithm is designed in such a manner that the SOR parameter is computed appropriately to guarantee convergence. Numerical examples are presented.     

Fracture strength of various lay-ups of carbon/epoxy laminates using the modified inherent flaw model

Modifications are made in the inherent flaw model of Waddoups, Eisenman and Kaminski (known as the WEK model) for accurate prediction of notched tensile strength of composite laminates containing a sharp notch. To examine the adequacy of the model, fracture data of center cracked carbon/epoxy composite laminates with various lay-ups are considered. The notched strength estimates are found to be close to the test results.